CORDIS Project
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This project explores the combination of low-valent bismuth catalysis and electrochemistry to create sustainable methods for forming carbon-carbon bonds. It focuses on the electrochemical behavior of bismuth complexes to facilitate the synthesis of organic molecules, particularly in challenging reactions like carboxyla…
The proposed work involves merging low-valent bismuth catalysis with electrochemistry to unlock eminently sustainable methods for C-C bond formation.
The research outlined herein would constitute the first systematic foray into electrocatalytic organobismuth manifolds for the synthesis of organic molecules.Well-defined monomeric Bi(I) pincer complexes have recently been used to activate redox-active esters and alkyl halides via 1-electron and 2-electron pathways, respectively.
In the first secti…
MAX PLANCK INSTITUT FUER KOHLENFORSCHUNG
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