CORDIS Project
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This project aims to innovate radical chemistry by developing a method for activating alpha,alpha-diborylated alkanes through a combination of photoredox catalysis and boryl radical-mediated hydrogen atom transfer. This approach seeks to enable the synthesis of valuable aliphatic compounds that are typically challengin…
Aliphatic molecules are integral to every aspect of chemistry and radical chemistry has strong impact in their preparation.
However, radical reactions are heavily influenced by the polarity of these species, which ultimately controls their reactivty profile.Most notably, standard alkyl radicals are nucleophilic and therefore do not react with electron rich aromatics and olefins.
Electrophilic radicals display strong reactivity with these species but they are of limited synthetic value.This proje…
RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN
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