CORDIS Project
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This project investigates the use of carbene iridium complexes for efficient water oxidation, a crucial step in hydrogen production from water. The goal is to develop a robust catalytic system that can facilitate energy generation from renewable sources.
We have recently discovered a series of carbene iridium complexes that are highly active in water oxidation catalysis (Angew.
Chem.
Int.
Ed. 2010, 49, 9765, see also picture).
As the water oxidation half-cycle is the demanding (and thus far prohibitive) step when splitting water to oxygen and hydrogen, these iridium complexes hold great potential for the generation of hydrogen as fuel from renewable, non-fossil sources. A key component for the efficient water oxidation appears to be the mesoioni…
UNIVERSITY COLLEGE DUBLIN, NATIONAL UNIVERSITY OF IRELAND, DUBLIN
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