CORDIS Project
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This project investigates enantioselective metal enolate alkylation reactions using cooperative catalysis. The goal is to develop a new methodology for generating asymmetry in organic synthesis, which could lead to biologically relevant products and significant advancements in synthetic chemistry.
The reaction between a metal enolate ion and an alkyl halide (or equivalent) electrophile is one of the most useful process for the formation of carbon-carbon bond in organic synthesis.
We wish to develop enantioselective metal enolate alkylation reactions under cooperative Lewis base and Hydrogen-bond donor catalysis.
The combination of Lewis basic H-bond donor and metal enolate ion to interact cooperatively to both activate and organise the enolate towards the electrophilic component, be it al…
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