CORDIS Project
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This project develops a novel method for synthesizing complex organic molecules using a new reaction involving lithiated carbamates and boronic esters. The approach allows for high efficiency and stereocontrol, enabling the rapid production of biologically active polypropionates and other complex natural products.
The creation of new molecular entities and subsequent exploitation of their properties is central to a broad spectrum of research disciplines from medicine to materials but progress has been limited by the difficulties associated with chemical synthesis.
We are now proposing a fundamentally new strategy, which has the potential to revolutionise how we conduct complex organic synthesis.
The basic C–C bond-forming step involves the reaction of a lithiated carbamate with a boronic ester to give a h…
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