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The Gold3Cat project focuses on developing stable gold(III) complexes to enhance gold catalysis. By designing new ligands, the project aims to explore unique reactivity and selectivity in chemical reactions, particularly in hydroarylation and asymmetric synthesis, to improve the efficiency of complex molecule construct…
Over the last 20 years, gold catalysis has become a very efficient method for the rapid construction of complex and highly functionalized molecules.
However, gold catalysis is mainly limited to the activation of π-systems by Au(I) complexes.
Comparatively, Au(III) catalysis is poorly developed due to the rarity of stable but reactive Au(III) complexes.
But recent studies showed that judicious ligand design enables to stabilize Au(III) complexes and that switching from Au(I) to Au(III) leads to c…
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
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