CORDIS Project
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The project aims to revolutionize the synthesis of anilines by converting functionalized N-cyclohexyl derivatives into N-aryl derivatives using a novel triple catalysis approach. This method seeks to simplify the production of complex organic molecules for use in pharmaceuticals and agrochemicals.
Anilines and their derivatives are integral organic molecules with application as medicines, agrochemicals and organic materials.
Over the last 30 years, the Buchwald-Hartwig and Ullmann cross-couplings have dominated the area of aromatic amination.
These reactions involve palladium- or copper-catalyzed C-N bond formation between a halogenated aromatic and an amine.
Only aromatics that have been halogenated will react with the metal catalysts and undergo cross-coupling.
Therefore, although these…
RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN
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