CORDIS Project
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This project explores new metal complexes created using innovative indenyl-type ligands. The focus is on stabilizing oxo and peroxo complexes and investigating their potential in hydroamination reactions.
The group of D.
Bourissou has recently reported a new family of indenyl-type ligands bearing one or two coordinating side-arms.
These new ligands have allowed the preparation of several metal complexes (Zr, Rh, Pd) exhibiting original coordination modes: eta-1 indenyl and 2-indenylidene.
In this project, we envision to take advantage of the strong sigma-donor character of such original 2-indenylidene pincer ligands (i) to stabilise oxo and peroxo complexes of late transition metals and (ii) to e…
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS
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