CORDIS Project
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This project explores a new method using copper(II) to selectively modify C–H bonds in aromatic compounds, focusing on arylacetamides. The approach aims to facilitate the synthesis of antibiotics like arylomycin A2 and its analogues, potentially addressing bacterial resistance and improving disease treatment.
This proposal details a new Cu(II) catalysed reactivity concept that will enable the selective C–H bond functionalisation of an important class of aromatic compounds.
In particular, a meta-selective C–H arylation of arylacetamides will be the focus of this study.
Furthermore, this strategy could also be used to assemble the potent antibiotic, arylomycin A2 as well as facilitate the convenient synthesis of analogues that could be used to probe bacterial resistance, leading to new antibiotic treat…
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