CORDIS Project
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This project focuses on understanding and designing new aromatic systems with Möbius topology by evaluating the factors affecting their viability, such as aromaticity, strain, and metallation. It employs computational techniques to analyze their electronic and photophysical properties under varying conditions.
The concept of Möbius aromaticity has become a very popular topic in the literature.
However, the synthesis of a viable aromatic Möbius system has been a challenge for Chemistry for 40 years.
Herges and collaborators finally solved this problem combining a normal planar conjugated structure with a rigid “prefabricated” belt-shaped conjugated segment.
After this seminal work more annulenic Möbius aromatic systems have not been reported due to their small cis-trans isomerisation barriers.
However,…
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