CORDIS Project
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This project explores the coordination chemistry of three-dimensional transition metals with new types of ligands. It aims to create novel complexes that can activate small molecules, enhancing our understanding of their molecular structures.
The coordination chemistry of 3d transition metals with covalently tethered N-heterocyclic carbene (NHC) ligands is almost completely unexplored.
In this project, we will develop a completely new and stereo-electronically more versatile type of NHC ligand functionalized with anionic amido or phosphido donor groups.
Our ligands will enable the development of a new family of three-coordinate complexes of low-valent chromium, manganese iron, cobalt and nickel, represented by 1 and 2.
The three coor…
THE UNIVERSITY OF MANCHESTER
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