CORDIS Project
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This project aims to enhance the reactivity of p-block elements in their stable oxidation states for bond activation and catalysis. It explores innovative chemical strategies to enable new catalytic transformations using abundant elements.
State-of-the-art strategies for p-block element-based bond activations predominantly rely on the activity of low-valent species (e.g., silylenes).
However, during bond activation, those species usually collapse into the deep thermodynamic sinks of their standard oxidation states, precluding any catalytic cycles.
The present proposal pCX4All develops new concepts that add unique reactivity to the p-block elements Al, Ga, Si, Ge, Sn and P in their stable oxidation states.
This is achieved by the g…
RUPRECHT-KARLS-UNIVERSITAET HEIDELBERG
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