CORDIS Project
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This project develops a gold-catalyzed method for synthesizing complex 1,3-azoles, which are important in pharmaceuticals and materials science. It aims to optimize reaction conditions and explore the application of these compounds in organocatalysis, enhancing the efficiency of chemical synthesis.
Cycloaddition reactions are extremely potent methods to form complex heterocycles.
However, [3+2]-cycloadditions across alkynes are generally ineffective for the formation of 1,3-azoles which are key constituents of natural products, pharmaceuticals and materials.
This project aims to establish a convergent and readily applicable gold-catalysed formal [3+2]-cycloaddition strategy to prepare diverse highly-substituted 1,3-azoles and related heteroaromatic structures.
Reaction discovery and optimi…
THE UNIVERSITY OF BIRMINGHAM
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